I. Process introduction
When using sulfuric acid as decomposition agent to dispose boron and magnesium mineral and produce boric acid, major elements of mother liquid are MgSO4 and H3BO3. Purify mother liquid (or use magnesium sulfate heptahydrate as raw material and conduct purification treatment through dissolution) to obtain pure magnesium solution, then use bicarbonate as precipitant, react with the magnesium therein under certain concentration and temperature condition to generate basic magnesium carbonate precipitation. Through ageing, rinsing, dehydrating and drying, produce medical (heavy) magnesium carbonate. Magnesium carbonate mother liquid reacts with alkali to volatilize ammonia, collect ammonia water and recycle.
Use the produced magnesium carbonate as precursor to control different process conditions, and produce high-purity magnesium oxide through calcination, pulverization, grading and packaging.
II. Technical Advancement
Boron yield is above 85%, and magnesium conversion rate is over 82%. The produced magnesium carbonate is slightly fine spherical crystal, having good dispersion property and flowability, which is in conformity with American medical standard. Magnesium oxide is in conformity with the standard of Second Edition of 2005 Pharmacopoeia of the Peoples Republic of China. Boric acid product quality is in conformity with the standard of product in the same category in Chile.
Light magnesium carbonate and magnesium oxide of all grades can also be produced by controlling different process conditions.
III. Market Prospect
Magnesium salt products represented by magnesium oxide and magnesium carbonate have prospecting international market situation, Chinese annual export volume accounts for about 60% of aggregate production, belonging to the important products earning foreign exchange through export. With the construction and development of national economy, domestic medicine, food, rubber, plastics, electronics, fire-proof material, domestic chemical engineering, ceramics, metallurgy and other industries have growing demand for magnesiumcompound, and the market demand is prosper. Therefore, its market and development prospect is very broad.
IV. Technical Sources
Industrialization technology. This process was successfully researched and developed by our Research Institute in 2003, and our Research Institute took the lead to realize industrialization in Shandong Hongji Chemical Industry Co., Ltd. and Zhongyuan Chemical Industry Co., Ltd. in 2005. It has formed the annual production capacity of boric acid 20,000t, medicinal grade high-purity magnesium carbonate 18,000t and medicinal magnesium oxide 6,000t. Through constant improvement and verification in the practice, this process has become the only domestic mature boron magnesium comprehensive utilization industrialization technology that has been successfully applied in industrial practice.
V. Product Quality
Boric acid product quality is in conformity with the standard of product in the same category in Chile or GB538-2006 prime grade product standard. Ton product profit is 1,200-1,600 Yuan; medical magnesium carbonate is in conformity with the standard of Second Edition of 2005 Pharmacopoeia of the Peoples Republic of China. Ton product profit is 3,600 Yuan; and medical magnesium oxide is in conformity with the standard of Second Edition of 2005 Pharmacopoeia of the Peoples Republic of China.
VI. Investment Scale
According to annual production of high quality boric acid 5,000t and co-production medicinal (heavy) magnesium carbonate 4,000t, the required equipment investment is 5 million Yuan, including magnesium carbonate investment 2 million Yuan; in case of co-production magnesium oxide, equipment investment 1.5 million Yuan should be increased.
VII. Environmental Protection
Boric acid mother liquid is comprehensively utilized, magnesium carbonate mother liquid is used in ammonia recovery without effluent discharge. Boric sludge generated during process is used in brick making or compound fertilizer manufacturing, causing no disadvantageous impact on environment.
VIII. Economic Benefits
High additional value, extremely big profit space and significant economic benefits.
IX. Form of Cooperation:
Technical transfer. Taking responsibility for process flow design, supporting equipment of standard equipment, non-standard equipment manufacture design, equipment is plane layout design, equipment installation design, pipe network design, equipment installation guidance, equipment commissioning, production commissioning, training for production engineers, analysis staff and technicians, process operation specifications, raw material and product analysis method, and preparation of intermediate control analysis method; ensuring output, yield and quality to reach the standard; and undertaking turn-key projects.